Synthesis of unsymmetrical biaryls from arylsilacyclobutanes

被引：101

作者：

Denmark, SE ^{[1
]}

Wu, ZC ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Roger Adams Lab, Urbana, IL 61801 USA

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 09期

关键词：

D O I：

10.1021/ol991054k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Aryl(fluoro)silacyclobutanes and aryl(chloro)silacyclobutanes have been found to undergo cross-coupling reactions with aryl iodides. The rate of reaction and extent of homocoupling were dramatically affected by the addition of ligands for the palladium catalyst. With (t-Bu)(3)P a wide range of electronically and structurally diverse unsymmetrical biaryls have been prepared in good to excellent yields.

引用

页码：1495 / 1498

页数：4

共 27 条

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