SSH2S: Hydrogen storage in complex hydrides for an auxiliary power unit based on high temperature proton exchange membrane fuel cells

被引:48
作者
Baricco, Marcello [1 ,2 ]
Bang, Mads [3 ]
Fichtner, Maximilian [4 ]
Hauback, Bjorn [5 ]
Linder, Marc [6 ]
Luetto, Carlo [7 ]
Moretto, Pietro [8 ]
Sgroi, Mauro [9 ]
机构
[1] Univ Turin, Dept Chem, Via P Giuria 7, I-10125 Turin, Italy
[2] Univ Turin, NIS, Via P Giuria 7, I-10125 Turin, Italy
[3] Serenergy AS, Lyngvej 8, DK-9000 Aalborg, Denmark
[4] Karlsruhe Inst Technol, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
[5] Inst Energy Technol, Phys Dept, POB 40, NO-2027 Kjeller, Norway
[6] Geraman Aerosp Ctr DLR, Inst Engn Thermodynam, Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
[7] Tecnodelta Srl, Via F Parigi 5-H, I-10034 Chivasso, TO, Italy
[8] European Commiss, JRC, Directorate Energy Transport & Climate, Westerduinweg 3, NL-1755 LE Petten, Netherlands
[9] Ctr Ric Fiat SCpA, Str Torino 50, I-10043 Orbassano, TO, Italy
关键词
Hydrogen storage; High temperature fuel cell; Auxiliary power unit; Lithium amide; Magnesium hydride; METAL HYDRIDE; COMBINATION REACTOR; IMPACTS ASSESSMENT; SYSTEM; PERFORMANCE; TANK; OPTIMIZATION; PROCESSOR; DESIGN; SORPTION;
D O I
10.1016/j.jpowsour.2016.12.107
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The main objective of the SSH2S (Fuel Cell Coupled Solid State Hydrogen Storage Tank) project was to develop a solid state hydrogen storage tank based on complex hydrides and to fully integrate it with a High Temperature Proton Exchange Membrane (HT-PEM) fuel cell stack. A mixed lithium amide/magnesium hydride system was used as the main storage material for the tank, due to its high gravimetric storage capacity and relatively low hydrogen desorption temperature. The mixed lithium amide/magnesium hydride system was coupled with a standard intermetallic compound to take advantage of its capability to release hydrogen at ambient temperature and to ensure a fast start-up of the system. The hydrogen storage tank was designed to feed a 1 kW HT-PEM stack for 2 h to be used for an Auxiliary Power Unit (APU). A full thermal integration was possible thanks to the high operation temperature of the fuel cell and to the relative low temperature (170 C-circle) for hydrogen release from the mixed lithium amide/magnesium hydride system. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:853 / 860
页数:8
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