Preparation of (R)- and (S)-1-adamantyl-9-anthrylmethanol.: Conformational study and their behaviour as chiral solvating agents

被引：11

作者：

Almer, S ^{[1
]}

Cervelló, E ^{[1
]}

Jaime, C ^{[1
]}

Virgili, A ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 19期

关键词：

D O I：

10.1016/S0957-4166(99)00398-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiopure forms of 1-adamantyl-9-anthrylmethanol were prepared and a conformational study was carried out by MM and NOE transfer methodologies. The absolute configuration was determined by combining dynamic NMR and theoretical calculations of the carbamate derivatives. The activity as a chiral solvating agent was tested in the presence of oxygenated functional groups. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3719 / 3725

页数：7

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