Bromine catalyzed conversion of S-tert-butyl groups into versatile and, for self-assembly processes accessible, acetyl-protected thiols

被引：30

作者：

Blaszczyk, A

Elbing, M

Mayor, M

机构：

[1] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[2] Fac Commod Sci, PL-60967 Poznan, Poland

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 19期

关键词：

D O I：

10.1039/b408677e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The facile and efficient conversion of a tert-butyl protecting group to an acetyl protecting group for thiols by catalytic amounts of bromine in acetyl chloride and the presence of acetic acid has been developed. The fairly mild reaction conditions are of particular interest for new protecting group strategies for sulfur functionalised target structures.

引用

页码：2722 / 2724

页数：3

共 22 条

[1]

Aliev I A, 1991, SULFUR LETT, V12, P123

[2] Organization of 'nanocrystal molecules' using DNA [J].