Biomimetic synthesis and absolute configuration of (-)-tanzanene

被引：10

作者：

Paknikar, SK

Fondekar, KP

Mayer, R

机构：

[1] GOA UNIV,DEPT CHEM,TALEGAON PLATEAU 403203,GOA,INDIA

[2] UNIV BONN,INST PHARMAZEUT,D-53115 BONN,GERMANY

来源：

NATURAL PRODUCT LETTERS | 1996年 / 8卷 / 04期

关键词：

(-)-tanzanene; 4+2]cycloaddition; (-)-allo-aromadendrene; 6-methylene-2,4-cyclohexadiene-1-one; o-quinone methide; hetero Diels-Alder reaction; Uvaria;

D O I：

10.1080/10575639608044903

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Biomimetic synthesis of (-)-tanzanene (1) from (-)-alloaromadendrene (4) is reported. This first synthesis of (-)-tanzanene also established its absolute configuration as shown in 1.

引用

页码：253 / 256

页数：4

共 5 条

[1]

BUCHI G, 1969, J AM CHEM SOC, V91, P6473

[2] Studies on the field of the phenol formaldehye resins Iota. Announcement - The reaction of phenol alcohol with unsaturated substances [J].