NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation

被引：24

作者：

Godard, C

Callaghan, P

Cunningham, JL

Duckett, SB ^{[1
]}

Lohman, JAB

Perutz, RN

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Bruker BioSpin, Coventry CV4 9GH, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 23期

关键词：

D O I：

10.1039/b208007a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low temperature in-situ UV irradiation of toluene solutions containing bis(alkene) rhodium complexes and parahydrogen in conjunction with NMR monitoring enables the characterisation of unstable eta(2)-solvent complexes and dihydrogen activation products.

引用

收藏

页码：2836 / 2837

页数：2

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