The olefinic aldol reaction. Addition of zincated hydrazone to vinylsilane

被引：33

作者：

Nakamura, E

Kubota, K

机构：

[1] Department of Chemistry, University of Tokyo, Tokyo 113, Bunkyo-ku

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(97)01712-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A zincated N,N-dimethylhydrazone of a ketone bearing a BuZn(II) countercation undergoes intermolecular addition to a vinylsilane to afford the hydrazone of a 2-(2-silylethyl)ketone in good yield, providing a new synthetic route to functionalized carbonyl compounds. (C) 1997 Elsevier Science Ltd.

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页码：7099 / 7102

页数：4

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