The gelation of CO2:: A sustainable route to the creation of microcellular materials

被引：199

作者：

Shi, C

Huang, Z

Kilic, S

Xu, J

Enick, RM

Beckman, EJ

Carr, AJ

Melendez, RE

Hamilton, AD

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Univ Pittsburgh, Dept Chem & Petr Engn, Pittsburgh, PA 15261 USA

来源：

SCIENCE | 1999年 / 286卷 / 5444期

关键词：

D O I：

10.1126/science.286.5444.1540

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Compounds with strong thermodynamic affinity for carbon dioxide (CO2) have been designed and synthesized that dissolve in CO2, then associate to form gels. Upon removal of the CO2, these gels produced free-standing foams with cells with an average diameter smaller than 1 micrometer and a bulk density reduction of 97 percent relative to the parent material.

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页码：1540 / 1543

页数：4

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