Investigation of Flexible Organic Ligands in the Molybdate System: Delicate Influence of a Peripheral Cluster Environment on the Isopolymolybdate Frameworks

被引：75

作者：

Dong, Bao-xia ^{[1
]}

Xu, Qiang ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; PHOTOCHROMIC PROPERTIES; OCTAMOLYBDATE CLUSTERS; BETA-OCTAMOLYBDATE; BUILDING-BLOCKS; GUEST-SORPTION; POLYOXOMETALATE; COMPLEX;

D O I：

10.1021/ic900128t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By introducing the flexible ligands into the molybdate system, 12 novel isopolymolybdate frameworks based on four types of [Mo8O26](4-) isomers (theta, beta, gamma, and delta) and one kind of [Mo3O10](2-) polyoxcanion were obtained. Structural analyses indicate that, during the self-assembly and crystallization process, the change of metal ions and ligands can result in the formation of different peripheral cluster environments which promote the kinetic preference of one isomeric form over another or both.

引用

页码：5861 / 5873

页数：13

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