Enantioselective catalytic ring opening of epoxides with carboxylic acids

被引：275

作者：

Jacobsen, EN

Kakiuchi, F

Konsler, RG

Larrow, JF

Tokunaga, M

机构：

[1] Department of Chemistry, Harvard University, Cambridge

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 05期

基金：

日本学术振兴会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(96)02414-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chiral Co(salen) complex 3 is an effective catalyst for the asymmetric ring-opening of meso epoxides with benzoic acid. Enantioselectivities of 55-93% were obtained with a range of substrates. (C) 1997, Elsevier Science Ltd.

引用

页码：773 / 776

页数：4

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