Modeling of the retention of atrazine and dimethoate with nanofiltration

被引:14
作者
Ahmad, A. L. [1 ]
Tan, L. S. [1 ]
Shukor, S. R. Abd. [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Seberang Prai Selatan, Pulau Pinang, Malaysia
关键词
Nanofiltration; Dimethoate; Atrazine; Organic molecules; Spiegler-Kedem; MULTIPLE SOLUTES SYSTEM; REVERSE-OSMOSIS; IRREVERSIBLE THERMODYNAMICS; AQUEOUS-SOLUTION; MEMBRANES; PERFORMANCE; REJECTION; MOLECULES; RECOVERY; SALT;
D O I
10.1016/j.cej.2008.07.015
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The present study aims to investigate the viability of using Spiegler-Kedem model to predict the retention of atrazine and dimethoate with nanofiltration using NF90 in stirred cell condition. Spiegler-Kedem model is the thermodynamics of irreversible processes in which no particular mechanism of transport and structure of membrane is specified. The Spiegler-Kedem transport equations were used to derive the reflection coefficient and solute permeability of the system. The model was successfully applied on the modeling of the organic molecules tested. It was found that Spiegler-Kedem model provided a good estimation of experimental value. The coefficient of determination (R-2) obtained for the fitted data was 0.9871 and 0.9692 for atrazine and dimethoate, respectively. (C) 2008 Published by Elsevier B.V.
引用
收藏
页码:280 / 286
页数:7
相关论文
共 28 条
[1]   The role of pH in nanofiltration of atrazine and dimethoate from aqueous solution [J].
Ahmad, A. L. ;
Tan, L. S. ;
Shukor, S. R. Abd. .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 154 (1-3) :633-638
[2]   Dimethoate and atrazine retention from aqueous solution by nanofiltration membranes [J].
Ahmad, A. L. ;
Tan, L. S. ;
Shukor, S. R. Abd. .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 151 (01) :71-77
[3]   Mathematical modeling of multiple solutes system for reverse osmosis process in palm oil mill effluent (POME) treatment [J].
Ahmad, A. L. ;
Chong, M. F. ;
Bhatia, S. .
CHEMICAL ENGINEERING JOURNAL, 2007, 132 (1-3) :183-193
[4]   Mathematical modeling and simulation of the multiple solutes system for nanofiltration process [J].
Ahmad, AL ;
Chong, MF ;
Bhatia, S .
JOURNAL OF MEMBRANE SCIENCE, 2005, 253 (1-2) :103-115
[5]   Rejection and modelling of sulphate and potassium salts by nanofiltration membranes: neural network and Spiegler-Kedem model [J].
Al-Zoubi, H. ;
Hilal, N. ;
Darwish, N. A. ;
Mohammad, A. W. .
DESALINATION, 2007, 206 (1-3) :42-60
[6]  
Ballantyne B., 2004, PESTICIDE TOXICOLOGY
[7]  
BEITZ H, 1994, PESTICIDES GROUNDWAT
[8]   Analysis of polarized layer resistance during ultrafiltration of PEG-6000: an approach based on filtration theory [J].
Bhattacharjee, C ;
Datta, S .
SEPARATION AND PURIFICATION TECHNOLOGY, 2003, 33 (02) :115-126
[9]  
Bhattacharya A, 2004, REV CHEM ENG, V20, P111
[10]  
Carson R, 1962, Silent spring