A novel immobilised cobalt(III) oxidation catalyst

被引:67
作者
Das, BK [1 ]
Clark, JH [1 ]
机构
[1] Univ York, Dept Chem, Clean Technol Ctr, York YO10 5DD, N Yorkshire, England
关键词
D O I
10.1039/b000535p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A complex form of cobalt(III) has been successfully immobilised on a chemically modified silica and proven to be an active catalyst for the selective oxidation of alkylaromatics using air as the source of oxygen and in the absence of solvent.
引用
收藏
页码:605 / 606
页数:2
相关论文
共 14 条
  • [1] Environmentally friendly catalysis using supported reagents: Catalytic epoxidation using a chemically modified silica gel
    Butterworth, AJ
    Clark, JH
    Walton, PH
    Barlow, SJ
    [J]. CHEMICAL COMMUNICATIONS, 1996, (16) : 1859 - 1860
  • [2] Catalytic oxidation of ethylbenzene to acetophenone using alumina-supported dichromate: Process optimisation and development of a continuous process
    Chisem, IC
    Martin, K
    Shieh, MT
    Chisem, J
    Clark, JH
    Jachuck, R
    Macquarrie, DJ
    Rafelt, J
    Ramshaw, C
    Scott, K
    [J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1997, 1 (05) : 365 - 369
  • [3] Catalytic oxidation of alkyl aromatics using a novel silica supported Schiff base complex
    Chisem, IC
    Rafelt, J
    Shieh, MT
    Chisem, J
    Clark, JH
    Jachuck, R
    Macquarrie, D
    Ramshaw, C
    Scott, K
    [J]. CHEMICAL COMMUNICATIONS, 1998, (18) : 1949 - 1950
  • [4] Catalysis of liquid phase organic reactions using chemically modified mesoporous inorganic solids
    Clark, JH
    Macquarrie, DJ
    [J]. CHEMICAL COMMUNICATIONS, 1998, (08) : 853 - 860
  • [5] Green Chemistry: challenges and opportunities
    Clark, JH
    [J]. GREEN CHEMISTRY, 1999, 1 (01) : 1 - 8
  • [6] CLARK JH, 1992, SUPPORTED REAGENTS P
  • [7] Hronec M., 1983, OXID COMMUN, V3, P303
  • [8] The stability of chromium in CrAPO-5, CrAPO-11, and CrS-1 during liquid phase oxidations
    Lempers, HEB
    Sheldon, RA
    [J]. JOURNAL OF CATALYSIS, 1998, 175 (01) : 62 - 69
  • [9] MACQUARRIE DJ, 2000, IN PRESS PHILOS T A
  • [10] Modified silicas for clean technology
    Price, PM
    Clark, JH
    Macquarrie, DJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (02): : 101 - 110