A diamondoid network of tetrakis(acetamidato)dirhodium in mixed oxidation states linked by μ4-iodide having a 105 enhancement of its electrical conductivity by water molecules of hydration

被引：69

作者：

Fuma, Y ^{[1
]}

Ebihara, M ^{[1
]}

Kutsumizu, S ^{[1
]}

Kawamura, T ^{[1
]}

机构：

[1] Gifu Univ, Fac Engn, Dept Chem, Gifu 5011193, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 39期

关键词：

D O I：

10.1021/ja047421r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mixed oxidation-state (Rh24+ and Rh25+) compound, [{Rh2(acam)4}2I]n·6nH2O (Hacam = acetamide), has been synthesized. The compound has a nonpenetrating diamondoid arrangement of {Rh2(acam)4} units linked by μ4-iodides. All of the dirhodium units are crystallographically equivalent, as are all of the iodide atoms. The magnetic susceptibility of this compound shows that one-half of the Rh2 units are in the Rh25+ oxidation state with one odd electron and the other half in the closed-shell Rh24+ state. Its electrical conductivity is 1.4 × 10-3 S cm-1 (pellets, room temperature) and oscillates over the range of 105 orders of magnitude during dehydration-rehydration cycles of interstitial water molecules. Copyright © 2004 American Chemical Society.

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页码：12238 / 12239

页数：2

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