Rate constants for reaction of a fluorous tin hydride reagent with primary alkyl radicals

被引：31

作者：

Horner, JH

Martinez, FN

Newcomb, M

Hadida, S

Curran, DP

机构：

[1] WAYNE STATE UNIV,DEPT CHEM,DETROIT,MI 48202

[2] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 16期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(97)00489-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rate constants for 6-exo cyclization of the 7,7-diphenyl-6-heptenyl radical (3) in benzotrifluoride (BTF, PhCF3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate constants of reactions of the fluorous tin hydride reagent tris(2-(perfluorohexyl)ethyl)tin hydride with primary alkyl radicals. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：2783 / 2786

页数：4

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