Molecular paneling of rac-1,1′-bi-2-naphthol/∼ate (BINOL/BINOLAT):: hydrogen-bonded assembly of [M(NH3)4 or 6]2+ complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2-(BINOL)2}-strands

被引：14

作者：

Paul, B

Näther, C

Walfort, B

Fromm, KM

Zimmermann, B

Lang, H

Janiak, C

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany

[3] TU Chemnitz, Inst Anorgan Chem, D-09111 Chemnitz, Germany

[4] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

CRYSTENGCOMM | 2004年 / 6卷

关键词：

D O I：

10.1039/b410933c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The naphthyl-paneled cavities in the {[BINOLAT](2-)(BINOL)(2)}-host strands in the structures of [M(NH3)(n)](2+)[BINOLAT](2-)(BINOL)(2) accommodate the [M(NH3)(n)](2+)-guest cation through second-sphere N-H...O hydrogen bonding irrespective of the size ( M = Ni or Cd, n = 6) or coordination polyhedron ( tetrahedron for M = Zn, n = 4 or octahedron for M = Ni, Cd).

引用

页码：293 / 297

页数：5

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