Chiral recognition of tetrahelicene dicarboxylic acid by linear dextrins

被引：22

作者：

Kano, K

Negi, S

Takaoka, R

Kamo, H

Kitae, T

Yamaguchi, M

Okubo, H

Hirama, M

机构：

[1] TOHOKU UNIV, INST PHARMACEUT, AOBA KU, SENDAI, MIYAGI 98077, JAPAN

[2] TOHOKU UNIV, GRAD SCH SCI, DEPT CHEM, AOBA KU, SENDAI, MIYAGI 98077, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 08期

关键词：

D O I：

10.1246/cl.1997.715

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recognition of the helicity of 1,12-dimethylbenzo[c]phenanthrene-5,8-dicarboxylic acid (1) by linear oligosaccharides has been studied by H-1 NMR spectroscopy and capillary zone electrophoresis. Both methods clearly indicate that maltotetraose, maltopentaose, maltohexaose, and maltoheptaose selectively complex with the (M)-isomer of 1 as a guest through hydrogen-bonding interaction in water.

引用

收藏

页码：715 / 716

页数：2

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