Time dependent light attenuation measurements used in studies of the kinetics of polymer crystallization

被引：12

作者：

Heck, B. ^{[1
]}

Kawai, T. ^{[1
]}

Strobl, G. ^{[1
]}

机构：

[1] Univ Freiburg, Inst Phys, D-79104 Freiburg, Germany

来源：

POLYMER | 2006年 / 47卷 / 15期

关键词：

polymer crystallization; spherulites; light scattering;

D O I：

10.1016/j.polymer.2005.11.098

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Results obtained for different samples of s-polypropylene and poly (ethylene-co-octene) demonstrated the usefulness of light attenuation measurements in investigations of polymer crystallization. The earlier stages with separated growing spheruilites fall in the range of Rayleigh-Debye-Gans scattering. Known relationships describing the dependence of the linear attenuation coefficient on the radius and the index of refraction of the spherulite can be applied in evaluations. The sensitivity of attenuation measurements is higher than that of conventional tools. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：5538 / 5543

页数：6

共 14 条

[1] LIGHT TRANSMISSION AND THE FORMATION AND DECAY OF SPHERULITES IN POLYTHENE [J].