The chemistry of pentavalent organobismuth reagents .14. Recent advances in the copper-catalyzed phenylation of amines.

被引：70

作者：

Arnauld, T ^{[1
]}

Barton, DHR ^{[1
]}

Doris, E ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

TETRAHEDRON | 1997年 / 53卷 / 12期

关键词：

D O I：

10.1016/S0040-4020(97)00133-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A reinvestigation of the copper-mediated phenylation of amines by Bi-v reagents is reported. The influence of the ligands bound to bismuth and the basicity of the amines have been examined. These results, combined with our previous observations, led to the development of a new system for the quantitative phenylation of selected hindered aliphatic and aromatic amines. (C) 1997 Elsevier Science Ltd.

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页码：4137 / 4144

页数：8

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