Viable use of 2-substituted thiazolidine-4-methanol diastereoisomeric mixtures during asymmetric borane reduction of aromatic ketones

被引：24

作者：

Calmes, M ^{[1
]}

Escale, F ^{[1
]}

Paolini, F ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,UMR CNRS 5810,LAB AMINOACIDES PEPTIDES & PROT,F-34095 MONTPELLIER 5,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 21期

关键词：

D O I：

10.1016/S0957-4166(97)00480-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of aromatic ketones by borane in the presence of the inseparable diastereoisomeric mixture of 2-substituted thiazolidine-4-methanol has been investigated. Modest to high enantiomeric excesses were obtained increasing with thiazolidine steric hindrance. (C) 1997 Elsevier Science Ltd.

引用

页码：3691 / 3697

页数：7

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