Novel synthesis of poly(3,4-ethylenedioxythiophene) nanotubes and hollow micro-spheres

被引:18
作者
Du, Xu-Sheng [1 ]
Zhou, Cui-Feng [1 ]
Mai, Yiu-Wing [1 ]
机构
[1] Univ Sydney, Sch Aerosp Mech & Mechatron Engn J07, Sydney, NSW 2006, Australia
基金
澳大利亚研究理事会;
关键词
PEDOT; Conductive polymer; Nanomaterials; Hollow sphere; Nanotube; Self assembly; POLY 3,4-ETHYLENEDIOXYTHIOPHENE; CHEMICAL POLYMERIZATION; POLYANILINE NANOFIBERS; FACILE SYNTHESIS; PEDOT; NANOPARTICLES; MICROSPHERES; CONDUCTIVITY; POLYSTYRENE; TEMPLATE;
D O I
10.1016/j.matlet.2009.04.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of poly(3,4-ethylenedioxythiophene) (PEDOT) nanomaterials are prepared in aqueous solution without using any organic solvent, acid, surfactant and porous hard template. PEDOT can be tuned into different shapes. such as nano-tubes, spheres and vesicle-like particles by simply adjusting the experiment conditions. The different nanostructured products show similar electrochemical voltammogram behavior, though XRD and FTIR analysis indicate some different doping level and crystallity between them. The formation of different shaped polymer particles is supposed to be associated with the self assembly growth of the formed reactive EDOT species. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1590 / 1593
页数:4
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