Water addition to a two-electron mixed-valence bimetallic center

被引：9

作者：

Veige, AS ^{[1
]}

Nocera, DG ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 17期

关键词：

D O I：

10.1039/b402426e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water adds to the two-electron mixed-valence Ir-2(0,II) core of Ir-2(tfepma)(3)Cl-2 (tfepma=MeN[P(OCH2CF3)(2)](2)) to cleanly generate an Ir-2(I,III) hydride. Dehydrohalogenation across the Ir-Ir bond returns the complex to an Ir-2(0,II) species.

引用

页码：1958 / 1959

页数：2

共 12 条

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