Water addition to a two-electron mixed-valence bimetallic center

被引:9
作者
Veige, AS [1 ]
Nocera, DG [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
关键词
D O I
10.1039/b402426e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water adds to the two-electron mixed-valence Ir-2(0,II) core of Ir-2(tfepma)(3)Cl-2 (tfepma=MeN[P(OCH2CF3)(2)](2)) to cleanly generate an Ir-2(I,III) hydride. Dehydrohalogenation across the Ir-Ir bond returns the complex to an Ir-2(0,II) species.
引用
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页码:1958 / 1959
页数:2
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