Polarization effects in time resolved incoherent anti-Stokes Raman spectroscopy

被引：17

作者：

Hofmann, M ^{[1
]}

Zurl, R ^{[1
]}

Graener, H ^{[1
]}

机构：

[1] UNIV HALLE WITTENBERG,FACHBEREICH PHYS,D-06099 HALLE,GERMANY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 15期

关键词：

D O I：

10.1063/1.472473

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recently the anti-Stokes spectroscopy after strong vibrational excitation via resonant absorption was rediscovered, for the study of population relaxation dynamics. A closer theoretical inspection of this experimental approach reveals that properly chosen polarization conditions allow the study of molecular reorientational motion. Furthermore the sign of alpha/gamma (the invariants of the Raman polarizability tensor) can be determined. Experimental data for chlorinated alkanes will be presented. (C) 1996 American Institute of Physics.

引用

页码：6141 / 6146

页数：6

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