Isotropic to nematic transition of aerosil-disordered liquid crystals

被引:54
作者
Caggioni, M [1 ]
Roshi, A
Barjami, S
Mantegazza, F
Iannacchione, GS
Bellini, T
机构
[1] Univ Milan, Dipartimento Chim Biochim & Biotecnol Med, INFM, Milan, Italy
[2] Worcester Polytech Inst, Dept Phys, Worcester, MA 01609 USA
[3] Univ Milano Bicocca, DIMESAB, INFM, Monza, Italy
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.93.127801
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present a high-resolution study of the isotropic to nematic phase transition of a low birefringence liquid-crystal compound incorporating an aerosil gel. Calorimetry, light scattering, and microscopy data coherently combine to allow for an accurate determination of the temperature dependence of the onset of the nematic state. The nematic order develops on cooling through two distinct processes while the nematic correlation length mildly decreases. We understand the doubling of the phase transition as due to a crossover from a random-dilution regime, where the silica gel couples to the scalar part of the nematic order parameter, to a low-T random-field regime, where the coupling induces distortions in the director field.
引用
收藏
页码:127801 / 1
页数:4
相关论文
共 21 条
[1]   Fluctuation mediated interaction and phase separation of nanoparticles in a liquid crystal solvent [J].
Bellini, T ;
Caggioni, M ;
Clark, NA ;
Mantegazza, F ;
Maritan, A ;
Pelizzola, A .
PHYSICAL REVIEW LETTERS, 2003, 91 (08) :857041-857044
[2]   Isotropic to smectic A phase transitions in a porous matrix: a case of multiporous phase coexistence [J].
Bellini, T ;
Clark, NA ;
Link, DR .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (01) :S175-S182
[3]   Nematics with quenched disorder: How long will it take to heal? [J].
Bellini, T ;
Buscaglia, M ;
Chiccoli, C ;
Mantegazza, F ;
Pasini, P ;
Zannoni, C .
PHYSICAL REVIEW LETTERS, 2002, 88 (24) :2455061-2455064
[4]   Nematics with quenched disorder: What is left when long range order is disrupted? [J].
Bellini, T ;
Buscaglia, M ;
Chiccoli, C ;
Mantegazza, F ;
Pasini, P ;
Zannoni, C .
PHYSICAL REVIEW LETTERS, 2000, 85 (05) :1008-1011
[5]   Universality and scaling in the disordering of a smectic liquid crystal [J].
Bellini, T ;
Radzihovsky, L ;
Toner, J ;
Clark, NA .
SCIENCE, 2001, 294 (5544) :1074-1079
[6]   Light-scattering measurement of the nematic correlation length in a liquid crystal with quenched disorder [J].
Bellini, T ;
Clark, NA ;
Degiorgio, V ;
Mantegazza, F ;
Natale, G .
PHYSICAL REVIEW E, 1998, 57 (03) :2996-3006
[7]  
CAGGIONI M, IN PRESS
[8]   Helium in aerogel [J].
Chan, M ;
Mulders, N ;
Reppy, J .
PHYSICS TODAY, 1996, 49 (08) :30-37
[9]   Determination of the order parameter and its critical exponent for nCB (n=5-8) liquid crystals from refractive index data [J].
Chirtoc, I ;
Chirtoc, M ;
Glorieux, C ;
Thoen, J .
LIQUID CRYSTALS, 2004, 31 (02) :229-240
[10]   Effect of a quenched random field on a continuous symmetry breaking transition:: Nematic to smectic-A transition in octyloxycyanobiphenyl-aerosil dispersions -: art. no. 021703 [J].
Clegg, PS ;
Stock, C ;
Birgeneau, RJ ;
Garland, CW ;
Roshi, A ;
Iannacchione, GS .
PHYSICAL REVIEW E, 2003, 67 (02) :13