Diels-Alder reactions using supercritical water as an aqueous solvent medium

被引：78

作者：

Korzenski, MB ^{[1
]}

Kolis, JW ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 32期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(97)01274-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of Diels-Alder reactions have been performed in supercritical water as a reaction medium. The rapid reaction of Diels-Alder reactions of cyclopentadiene and various electron poor dienophiles such as diethyl fumarate and acrylonitrile is observed in supercritical water, and leads to high yields of clean products without added catalysts. (C) 1997 Elsevier Science Ltd.

引用

页码：5611 / 5614

页数：4

共 14 条

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