Selective deposition of films of polypyrrole, polyaniline and nickel on hydrophobic/hydrophilic patterned surfaces and applications

被引：66

作者：

Huang, Z ^{[1
]}

Wang, PC ^{[1
]}

Feng, J ^{[1
]}

MacDiarmid, AG ^{[1
]}

Xia, YN ^{[1
]}

Whitesides, GM ^{[1
]}

机构：

[1] HARVARD UNIV, DEPT CHEM, CAMBRIDGE, MA 02138 USA

来源：

SYNTHETIC METALS | 1997年 / 85卷 / 1-3期

关键词：

polypyrrole and derivatives; polyaniline and derivatives; scanning electron microscopy; UV-Vis-NIR absorption;

D O I：

10.1016/S0379-6779(97)80279-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Computer-generated patterned hydrophobic films are produced on hydrophilic glass substrates by a microcontact ''stamp'' printing technique. The hydrophobic pattern is produced when the silicone elastomeric stamp (''inked'' with C18H37SiCl3) contacts the hydrophilic surface. Thin films of polypyrrole and polyaniline are deposited preferentially on the hydrophobic patterned surfaces from dilute aqueous solutions of the polymerizing monomer. Conversely, strongly adhering films of metals such as nickel are deposited selectively by an electroless process on the hydrophilic substrate surfaces. The properties of the polymers deposited on the hydrophilic and hydrophobic surfaces will be discussed as well as the application of the patterned polymer in liquid crystal displays.

引用

页码：1375 / 1376

页数：2

共 8 条

[1]

GREGORY RV, 1989, SYNTHETIC MET, V28, pC823, DOI 10.1016/0379-6779(89)90610-3

[2] PATTERNED SELF-ASSEMBLED MONOLAYERS FORMED BY MICROCONTACT PRINTING DIRECT SELECTIVE METALIZATION BY CHEMICAL-VAPOR-DEPOSITION ON PLANAR AND NONPLANAR SUBSTRATES [J].