Characterization of ZnO needle-shaped nanostructures grown on NiO catalyst-coated Si substrates

被引:53
作者
Kim, TY
Kim, JY
Lee, SH
Shim, HW
Lee, SH
Suh, EK
Nahm, KS [1 ]
机构
[1] Chonbuk Natl Univ, Nanomat Res Ctr, Chonju 561756, South Korea
[2] Chonbuk Natl Univ, Sch Chem Engn & Technol, Chonju 561756, South Korea
[3] Chonbuk Natl Univ, Dept Semicond Sci Technol, Chonju 561756, South Korea
[4] FED Project Team, Adv Inst Technol, Suwon 440600, South Korea
关键词
ZnO nanostructures; nano-needles; evaporation of Zn; characterization; growth mechanism;
D O I
10.1016/j.synthmet.2004.01.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
ZnO nanostructures were synthesized over NiO-coated Si substrate by a thermal evaporation of Zn powders in a vertical chemical vapor deposition (CVD) reactor. The ZnO nanostructures had a needle-like morphology and the diameter of the structures decreased linearly from the bottom to the top. The bottom diameters of the ZnO nano-needles normally ranged from 20 to 100 nm and the lengths were in the range of 2-3 mum. The clear lattice fringes in HRTEM image indicated the growth of good quality hexagonal single-crystal ZnO. Field emission (FE) characteristics of the ZnO nano-needles showed that the turn-on field was about 8.87 V/mum with a field enhancement factor of about 1099. The growth mechanism of the ZnO nano-needles was proposed on the basis of experimental data. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:61 / 68
页数:8
相关论文
共 41 条
[1]   Catalytic growth of high quality GaN micro-crystals [J].
Ahn, SH ;
Lee, SH ;
Nahm, KS ;
Suh, EK ;
Hong, MH .
JOURNAL OF CRYSTAL GROWTH, 2002, 234 (01) :70-76
[2]   Electron field emission from silicon nanowires [J].
Au, FCK ;
Wong, KW ;
Tang, YH ;
Zhang, YF ;
Bello, I ;
Lee, ST .
APPLIED PHYSICS LETTERS, 1999, 75 (12) :1700-1702
[3]  
Bonard JM, 2001, ADV MATER, V13, P184, DOI 10.1002/1521-4095(200102)13:3<184::AID-ADMA184>3.0.CO
[4]  
2-I
[5]   High vacuum chemical vapor deposition of cubic SiC thin films on Si(001) substrates using single source precursor [J].
Boo, JH ;
Lee, SB ;
Yu, KS ;
Sung, MM ;
Kim, Y .
SURFACE & COATINGS TECHNOLOGY, 2000, 131 (1-3) :147-152
[6]   Catalytic growth and characterization of gallium nitride nanowires [J].
Chen, CC ;
Yeh, CC ;
Chen, CH ;
Yu, MY ;
Liu, HL ;
Wu, JJ ;
Chen, KH ;
Chen, LC ;
Peng, JY ;
Chen, YF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (12) :2791-2798
[7]  
Choi YC, 2000, ADV MATER, V12, P746, DOI 10.1002/(SICI)1521-4095(200005)12:10<746::AID-ADMA746>3.0.CO
[8]  
2-N
[9]   Synthesis and optical properties of tetrapod-like zinc oxide nanorods [J].
Dai, Y ;
Zhang, Y ;
Li, QK ;
Nan, CW .
CHEMICAL PHYSICS LETTERS, 2002, 358 (1-2) :83-86
[10]   Self-assembled nanowire-nanoribbon junction arrays of ZnO [J].
Gao, PX ;
Wang, ZL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (49) :12653-12658