A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters

被引：236

作者：

Fang, Qian-Rong

Zhu, Guang-Shan ^{[1
]}

Jin, Zhao

Xue, Ming

Wei, Xiao

Wang, De-Jun

Qiu, Shi-Lun

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 37期

关键词：

cadmium; carboxylate ligands; clusters; materials science; supramolecular chemistry;

D O I：

10.1002/anie.200601668

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Flexible ligands afford large pores: A novel metal-organic framework constructed from cadmium carboxylate cluster secondary building units and formic acid bridging molecules is reported (see picture). This highly porous material displays rare body-centered cubic topology, as well as good sorption characteristics and optoelectronic properties. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6126 / 6130

页数：5

共 56 条

[1] [Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001
[2] Synthesis, structure determination and magnetic behaviour of the first porous hybrid oxyfluorinated vanado(III)carboxylate:: MIL-71 or VIII2(OH)2F2{O2C-C6H4-CO2}•H2O
Barthelet, K
Adil, K
Millange, F
Serre, C
Riou, D
Férey, G
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (09) : 2208 - 2212
[3] Synthesis, structure, and magnetic properties of two new vanadocarboxylates with three-dimensional hybrid frameworks
Barthelet, K
Riou, D
Nogues, M
Férey, G
[J]. INORGANIC CHEMISTRY, 2003, 42 (05) : 1739 - 1743
[4] [VIII(H2O)]3O(O2CC6H4CO2)3•(Cl, 9H2O) (MIL-59):: a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework
Barthelet, K
Riou, D
Férey, G
[J]. CHEMICAL COMMUNICATIONS, 2002, (14) : 1492 - 1493
[5] Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO
[6] 2-Y
[7] Batten S.R., 1998, ANGEW CHEM, V110, P1558, DOI DOI 10.1002/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO
[8] 2-7
[9] Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[10] 2-Z

← 1 2 3 4 5 6 →