A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters

被引:236
作者
Fang, Qian-Rong
Zhu, Guang-Shan [1 ]
Jin, Zhao
Xue, Ming
Wei, Xiao
Wang, De-Jun
Qiu, Shi-Lun
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
关键词
cadmium; carboxylate ligands; clusters; materials science; supramolecular chemistry;
D O I
10.1002/anie.200601668
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Flexible ligands afford large pores: A novel metal-organic framework constructed from cadmium carboxylate cluster secondary building units and formic acid bridging molecules is reported (see picture). This highly porous material displays rare body-centered cubic topology, as well as good sorption characteristics and optoelectronic properties. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6126 / 6130
页数:5
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