Effect of calcining and Al doping on structure and conductivity of Li7La3Zr2O12

被引：71

作者：

Chen, Ru-Jun ^{[1
]}

Huang, Mian ^{[1
]}

Huang, Wen-Ze ^{[1
]}

Shen, Yang ^{[1
]}

Lin, Yuan-Hua ^{[1
]}

Nan, Ce-Wen ^{[1
]}

机构：

[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China

来源：

SOLID STATE IONICS | 2014年 / 265卷

关键词：

Solid electrolyte; Solid-state reaction; Li ion conductivity; Garnet; Al doping; SOLID ELECTROLYTES; IONIC-CONDUCTIVITY; PHASE-TRANSITION; GARNET; DENSIFICATION; SUBSTITUTION; BATTERIES; SYSTEM; OXIDE; TA;

D O I：

10.1016/j.ssi.2014.07.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li7La3Zr2O12 (LLZ) ceramics with a garnet-type structure were prepared via the conventional solid-state reaction through different calcining processes. The calcining time and temperature were investigated. The results showed that the ionic conductivity of LLZ samples at room temperature decreased as the calcining temperature increased. The highest conductivity of 2.48 x 10(-4) S cm(-1) was obtained for the sample with the calcining process at 900 C. The amount of doping Al was also investigated, which showed different effects depending on the calcining process. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：7 / 12

页数：6

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