Azo Isocyanide Gold(I) Liquid Crystals, Highly Birefringent and Photosensitive in the Mesophase

被引：34

作者：

Arias, Javier ^{[1
]}

Bardaji, Manuel ^{[1
]}

Espinet, Pablo ^{[1
]}

Folcia, Cesar L. ^{[3
]}

Ortega, Josu ^{[2
]}

Etxebarria, Jesus ^{[3
]}

机构：

[1] Univ Valladolid, Fac Ciencias, IU CINQUIMA Quim Inorgan, E-47011 Valladolid, Spain

[2] Univ Basque Country, Dept Fis Aplicada 2, Fac Ciencia & Tecnol, E-48080 Bilbao, Spain

[3] Univ Basque Country, Dept Fis Mat Condensada, Fac Ciencia & Tecnol, E-48080 Bilbao, Spain

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

MESOGENIC PROPERTIES; NANOPHASE SEGREGATION; HALOGOLD(I) COMPLEXES; COPPER(II) COMPLEXES; MOLECULAR-STRUCTURE; SILVER MESOGENS; AZOBENZENE; BEHAVIOR; STORAGE; FILMS;

D O I：

10.1021/ic9005295

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds shown in the drawing, which are the first gold liquid crystals containing an uncoordinated azo group, show high birefringence in the mesophase, and their mesophases are photosensitive, being destabilized to isotropic liquid upon laser irradiation, because of trans-cis azo isomerization.

引用

页码：6205 / 6210

页数：6

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