Distinguishing between abstraction and addition as the first step in the reaction of a nitroxyl radical with cyclohexene

被引：29

作者：

Coseri, S ^{[1
]}

Ingold, KU

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

[2] Petru Poni Inst Macromol Chem, Iasi 6600, Romania

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 10期

关键词：

D O I：

10.1021/ol049527x

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

An unambiguous method for distinguishing between abstraction-addition and addition-abstraction mechanisms (and mixtures thereof) in the reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl with a specifically deuterated cyclohexene, 1,2-dideuteriocyclohexene, is demonstrated.

引用

页码：1641 / 1643

页数：3

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