High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteries

被引：156

作者：

Bazin, L. ^{[1
]}

Mitra, S. ^{[1
]}

Taberna, P. L. ^{[1
]}

Poizot, P. ^{[2
]}

Gressier, M. ^{[1
]}

Menu, M. J. ^{[1
]}

Barnabe, A. ^{[1
]}

Simon, P. ^{[1
]}

Tarascon, J. -M. ^{[2
]}

机构：

[1] Univ Toulouse 3, CIRIMAT, UMR 5085, F-31062 Toulouse 4, France

[2] Univ Picardie Jules Verne, LRCS, UMR 6007, F-80039 Amiens, France

来源：

JOURNAL OF POWER SOURCES | 2009年 / 188卷 / 02期

关键词：

Lithium-ion; Tin; Nanostructure; High rate; Electrolytic deposition; 3D microbatteries; LI-ION BATTERIES; ELECTROCHEMICAL LITHIATION; NEGATIVE ELECTRODES; NANOSTRUCTURED TIN; CAPACITY; OXIDE;

D O I：

10.1016/j.jpowsour.2008.12.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New high surface area nano-architectured copper current collectors have been designed based on simple electrodeposition method. The nano-architectured electrode design not only increases the effective surface area of the electrode but it is also very suitable for sustaining the mechanical and structural strain during electrochemical reaction. In this work, a nano-architectured Sn anode for Li-ion battery, based on Li-Sn alloying reaction, delivers very high cycle life and good power performance compared to planar tin films. This electrode could be successfully used in the field of 3D microbatteries. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：578 / 582

页数：5

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