Photodetachment of small water cluster anions in the near-infrared through the visible region

被引：33

作者：

Maeyama, T

Tsumura, T

Fujii, A

Mikami, N

机构：

[1] Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-77, Aoba-ku

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 264卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(96)01337-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water cluster anions were efficiently generated by attachment of slow photoelectrons ejected from laser-excited zirconium metal surface, and photodetachment cross sections for (H2O)(n)(-) (n = 2, 6, 7, and 11) were measured for a photon energy range of 0.74-2.54 eV. A gradual decrease of the cross section with the photon energy was observed for all the species. It was also found that the larger cluster exhibits the larger cross section. Size-dependent features of the spectra, were discussed in relation to the excess electron localization with evolution of the cluster size.

引用

页码：292 / 296

页数：5

共 22 条

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