Polylactide/Polyethylene/Organoclay Blend Nanocomposites: Structure, Mechanical and Thermal Properties

被引:24
作者
Abdolrasouli, Mehdi Haji [1 ]
Sadeghi, Gity Mir Mohamad [2 ]
Nazockdast, Hossein [2 ]
Babaei, Amir [1 ]
机构
[1] Amirkabir Univ Technol, Tehran 158754413, Iran
[2] Amirkabir Univ Technol, Dept Polymer Engn & Color Technol, Tehran 158754413, Iran
关键词
Blend; Nanocomposite; Polylactide; Structure; VISCOELASTIC PROPERTIES; POLY(LACTIC ACID); COPOLYMER; MORPHOLOGY; COMPOSITES; TOUGHNESS; BEHAVIOR; BARRIER;
D O I
10.1080/03602559.2014.909477
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
Structure and physical properties of PLA/PE/organoclay with and without compatibilizer (PE-g-MA) with PLA as a matrix phase were investigated by X-ray diffraction, transmission electron microscopy, rheometric mechanical spectrometer, thermal gravimetric analysis, dynamic mechanical thermal analysis and Mechanical experiments. Two types of compatibilized-blend nanocomposites were prepared by two feeding orders: (1) simultaneous feeding, (2) PLA/organoclay-based master batch. The XRD results showed an intercalated structure for nanocomposites. The mechanical results demonstrated that presence of PE and compatibilizer improved the elongation at break, while organoclay enhanced Young's modulus. Thermogravimetric analysis showed that organoclays could retard the thermal decomposition process in the nanocomposites.
引用
收藏
页码:1417 / 1424
页数:8
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