The first methyl antimony linked dimeric tetrathiafulvalene and tetraselenafulvalenes

被引：15

作者：

Ashizawa, Minoru ^{[1
]}

Yamamoto, Hiroshi M. ^{[1
]}

Nakao, Akiko ^{[1
]}

Kato, Reizo ^{[1
]}

机构：

[1] RIKEN, Condensed Mol Mat Lab, Wako, Saitama 3510198, Japan

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 50期

关键词：

X-RAY-STRUCTURE; MOLECULAR DONOR; ELECTRON-DONORS; COMPLEX; DERIVATIVES; SALTS;

D O I：

10.1016/j.tetlet.2006.10.025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In quest of novel organic donors, dimeric tetrathiafulvalene (TTF) and tetraselenafulvalenes (TSFs) linked by a single or double methyl antimony bridge, MeSb(TTF)2 (1), (MeSb)2(TSF)2 (cis-2 and trans-2), and MeSb(TSF)2 (3), have been synthesized. Singly bridged 1 and 3 show three pairs of redox waves, whereas doubly bridged cis-2 and trans-2 show two pairs of redox waves similarly to TSF. The X-ray structural analyses of neutral crystals, 1, cis-2 and trans-2, have succeeded. In their structures, antimony and chalcogen atoms form close intermolecular contacts useful in constructing supramolecular networks. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：8937 / 8941

页数：5

共 22 条

[1] OLIGOMERIC TETRATHIAFULVALENES - EXTENDED DONORS FOR INCREASING THE DIMENSIONALITY OF ELECTRICAL-CONDUCTION [J].

ADAM, M ;

MULLEN, K .

ADVANCED MATERIALS, 1994, 6 (06) :439-459

[2] STRUCTURE OF TRIPHENYLSTIBINE [J].

ADAMS, EA ;

KOLIS, JW ;

PENNINGTON, WT .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :917-919

[3] NEW PI-ELECTRON DONORS CONTAINING 2 TETRATHIAFULVALENE UNITS FUSED TO 1,4-DITHIINE AND A CONDUCTING CHARGE-TRANSFER COMPLEX WITH TETRACYANOQUINODIMETHANE [J].

AQAD, E ;

BECKER, JY ;

BERNSTEIN, J ;

ELLERN, A ;

KHODORKOVSKY, V ;

SHAPIRO, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (24) :2775-2776

[4] Synthesis and structures of highly conducting charge-transfer salts of selenium containing TTM-TTP derivatives [J].

Ashizawa, M ;

Akutsu, A ;

Noda, B ;

Nii, H ;

Kawamoto, T ;

Mori, T ;

Nakayashiki, T ;

Misaki, Y ;

Tanaka, K ;

Takimiya, K ;

Otsubo, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (08) :1449-1458

[5] Synthesis and properties of selenium containing TTM-TTP conductors [J].

Ashizawa, M ;

Nii, H ;

Kawamoto, T ;

Mori, T ;

Misaki, Y ;

Tanaka, K ;

Takimiya, K ;

Otsubo, T .

SYNTHETIC METALS, 2003, 135 (1-3) :627-628

[6] 1,4-dihydro-1,4-diphosphinine fused with two tetrathiafulvalenes [J].

Avarvari, N ;

Fourmigué, M .

CHEMICAL COMMUNICATIONS, 2004, (24) :2794-2795

[7] Neutral and dianionic organoantimony(III) dithiolene complexes:: Syntheses, X-ray crystal structures, and unexpected reactivity [J].

Avarvari, N ;

Fourmigué, M .

ORGANOMETALLICS, 2003, 22 (10) :2042-2049

[8] Two successive single crystal phase transitions involving the coordination sphere of antimony in PhSb(dmit), the first organo-antimony(III) dithiolene complex [J].

Avarvari, N ;

Faulques, E ;

Fourmigué, M .

INORGANIC CHEMISTRY, 2001, 40 (11) :2570-2577

[9] PREPARATION AND STRUCTURE OF A NOVEL ORGANOTELLURIUM DERIVATIVE - DI(TETRATHIAFULVALENE)TELLURIDE[(TTF)2TE] [J].

BECKER, JY ;

BERNSTEIN, J ;

BITTNER, S ;

SARMA, JARP ;

SHAHAL, L .

TETRAHEDRON LETTERS, 1988, 29 (47) :6177-6180

[10]

BRODERSON K, 1970, CHEM BER, V103, P799

← 1 2 3 →