Efficient and unique cooperation of three zinc(II) ions in the hydrolysis of diribonucleotides by a trinuclear zinc(II) complex

被引：93

作者：

Yashiro, M

Ishikubo, A

Komiyama, M

机构：

[1] Dept. of Chemistry and Biotechnology, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo-ku

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606505h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trinuclear Zn2+ complex is prepared using a ligand having six pyridine moieties, N, N, N', N', N '', N ''-hexakis(2-pyridylmethyl)[tris(2-aminoethyl)amine] (L(3)), and efficiently hydrolyses diribonucleotides at pH 7 and 50 degrees C, showing much greater activity than a dinuclear Zn(2)L(2) complex.

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页码：83 / 84

页数：2

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