Dynamic Figure Eight Loop Structure of meso-Tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0)

被引：24

作者：

Mori, Megumi ^{[1
]}

Okawa, Toshifumi ^{[1
]}

Lizuna, Noriko ^{[1
]}

Nakayama, Kana ^{[1
]}

Lintuluoto, Juha M. ^{[1
]}

Setsune, Jun-ichiro ^{[1
]}

机构：

[1] Kobe Univ, Dept Chem, Grad Sch Sci, Nada Ku, Kobe, Hyogo 6578501, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 09期

关键词：

SUBSTITUTED EXPANDED PORPHYRINS; ABSOLUTE-CONFIGURATION; INTERNAL-ROTATION; METAL-COMPLEX; CHEMISTRY; CYCLOPOLYPYRROLES; CYCLOOCTAPYRROLES; MACROCYCLES;

D O I：

10.1021/jo9001189

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3,3'-Diethyl substituents of the 2,2'-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/pi interactions and remarkably accelerate syn-anti conformational change of the 2,2'-bipyrrole components leading to helicity change in the figure eight loop of [32]octaphyrins.

引用

页码：3579 / 3582

页数：4

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