Lanthanide complexes in molecular recognition and chirality sensing of biological substrates

被引：596

作者：

Tsukube, H ^{[1
]}

Shinoda, S ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Sugimoto, Osaka 5588585, Japan

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 06期

关键词：

D O I：

10.1021/cr010450p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Applications of lanthanide complexes in molecular recognition and chirality sensing of biological substrates were discussed. On the basis of "exotic" coordination chemistry, the lanthanide cations and their complexes offer unique recognition and sensing of chiral biological substrates. Since their versatile coordination characteristics permit precise control of their structural, electronic, and other properties at the molecular level, a variety of intelligent complexes can be developed for recognition and sensing of amino acids and other biological substrates.

引用

页码：2389 / 2403

页数：15

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