Optimal adsorbent for adsorptive heat transformers: Dynamic considerations

被引:103
作者
Aristov, Yuriy I. [1 ]
机构
[1] Boreskov Inst Catalysis SB RAS, Novosibirsk 630090, Russia
来源
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID | 2009年 / 32卷 / 04期
基金
俄罗斯基础研究基金会;
关键词
Adsorption system; Heat transformer; Review; Adsorbent; Diffusivity; Heat transfer; Mass transfer; REAL OPERATING-CONDITIONS; WATER-ADSORPTION; SILICA-GEL; ISOBARIC STAGES; MASS-TRANSFER; GRAIN-SIZE; KINETICS; SIMULATION; SORPTION; MODEL;
D O I
10.1016/j.ijrefrig.2009.01.022
中图分类号
O414.1 [热力学];
学科分类号
摘要
Kinetic properties of the adsorbent can strongly affect dynamics of an adsorptive heat transformer. in this paper we describe a current methodology and start discussing a new approach for dynamic characterization and optimization of the system "adsorbent-heat exchanger" under conditions typical for heat transformation. Effect of the adsorbent nature, its grain size, residual non-adsorbable gas, heating rate, local shape of adsorption isobar on the adsorption dynamics and specific cooling (heating) power was studied for promising adsorbents of water (Fuji silica RD, FAM-Z02, SWS-1L). Based on these results some demands to an adsorbent optimal from the dynamic point of view have been discussed. (C) 2009 Elsevier Ltd and IIR. All rights reserved.
引用
收藏
页码:675 / 686
页数:12
相关论文
共 47 条
[1]  
Alefeld G., 1994, Heat conversion systems
[2]   EXPERIMENTAL AND THEORETICAL INVESTIGATION OF THE KINETICS OF THE SORPTION OF WATER-VAPOR BY SILICA-GEL [J].
ANDERSSON, JY ;
BJURSTROM, H ;
AZOULAY, M ;
CARLSSON, B .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1985, 81 :2681-2692
[3]   Kinetics of water sorption on SWS-1L (calcium chloride confined to mesoporous silica gel): Influence of grain size and temperature [J].
Aristov, YI ;
Glaznev, IS ;
Freni, A ;
Restuccia, G .
CHEMICAL ENGINEERING SCIENCE, 2006, 61 (05) :1453-1458
[4]  
ARISTOV YI, 2008, P INT C SORPT HEAT P, P31
[5]   A new methodology of studying the dynamics of water sorption/desorption under real operating conditions of adsorption heat pumps: Experiment [J].
Aristov, Yu. I. ;
Dawoud, B. ;
Glaznev, I. S. ;
Elyas, A. .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2008, 51 (19-20) :4966-4972
[6]   Universal relation between the boundary temperatures of a basic cycle of sorption heat machines [J].
Aristov, Yu. I. ;
Tokarev, M. M. ;
Sharonov, V. E. .
CHEMICAL ENGINEERING SCIENCE, 2008, 63 (11) :2907-2912
[7]   New family of solid sorbents for adsorptive cooling: Material scientist approach [J].
Aristov Yu.I. .
Journal of Engineering Thermophysics, 2007, 16 (2) :63-72
[8]  
Aristov Yu. I., 2005, P 6 INT SEM HEAT PIP, P342
[9]   Kinetics of water adsorption on silica Fuji Davison RD [J].
Aristov, Yuri I. ;
Tokarev, Mikhail M. ;
Freni, Angelo ;
Glaznev, Ivan S. ;
Restuccia, Giovanni .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 96 (1-3) :65-71
[10]   Novel Materials for Adsorptive Heat Pumping and Storage: Screening and Nanotailoring of Sorption Properties [J].
Aristov, Yury I. .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2007, 40 (13) :1242-1251