Chain tilt in alpha-poly(vinylidene fluoride)

被引：28

作者：

Lovinger, AJ ^{[1
]}

Keith, HD ^{[1
]}

机构：

[1] UNIV CONNECTICUT,INST MAT SCI,STORRS,CT 06269

来源：

MACROMOLECULES | 1996年 / 29卷 / 26期

关键词：

D O I：

10.1021/ma960674n

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of fold surfaces on the sphelurites of α-polyvinylidene fluoride (α-PVF2) is presented. Sphelurites of α-PVF2 crystallized are comprised of lamellae elongated along radially oriented axes. In a α-PVF2, the chain tilt are intermediate between those under banded sphelurites however, no chain tilt was observed on the crystals grown from dilute solutions in more conventional solvents.

引用

页码：8541 / 8542

页数：2

共 12 条

[1] CRYSTALLIZATION AND MORPHOLOGY OF A BACTERIAL THERMOPLASTIC - POLY-3-HYDROXYBUTYRATE [J].

BARHAM, PJ ;

KELLER, A ;

OTUN, EL ;

HOLMES, PA .

JOURNAL OF MATERIALS SCIENCE, 1984, 19 (09) :2781-2794

[2]

Bassett D.C., 1981, Principles of Polymer Morphology, V1st ed.

[3] THE MORPHOLOGY OF POLY(VINYLIDENE FLUORIDE) CRYSTALLIZED FROM BLENDS OF POLY(VINYLIDENE FLUORIDE) AND POLY(ETHYL ACRYLATE) [J].

BRIBER, RM ;

KHOURY, F .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1993, 31 (10) :1253-1272

[4] HABITS OF POLYETHYLENE CRYSTALS GROWN FROM PARAFFINIC SOLVENTS + FROM MELT [J].

KEITH, HD .

JOURNAL OF APPLIED PHYSICS, 1964, 35 (11) :3115-&

[5] Banding in polyethylene and other spherulites [J].

Keith, HD ;

Padden, FJ .

MACROMOLECULES, 1996, 29 (24) :7776-7786

[6] TWISTING ORIENTATION AND THE ROLE OF TRANSIENT STATES IN POLYMER CRYSTALLIZATION [J].

KEITH, HD ;

PADDEN, FJ .

POLYMER, 1984, 25 (01) :28-42

[7]

Lovinger A. J., 1982, DEV CRYSTALLINE POLY, V1, P195

[8] POLYMORPHIC TRANSFORMATIONS IN FERROELECTRIC COPOLYMERS OF VINYLIDENE FLUORIDE INDUCED BY ELECTRON-IRRADIATION [J].

LOVINGER, AJ .

MACROMOLECULES, 1985, 18 (05) :910-918

[9] ELECTRON-DIFFRACTION INVESTIGATION OF A HIGH-TEMPERATURE FORM OF POLY(VINYLIDENE FLUORIDE) [J].

LOVINGER, AJ ;

KEITH, HD .

MACROMOLECULES, 1979, 12 (05) :919-924

[10] CRYSTALLIZATION AND MORPHOLOGY OF MELT-SOLIDIFIED POLY(VINYLIDENE FLUORIDE) [J].

LOVINGER, AJ .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1980, 18 (04) :793-809

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