Artificial cells:: Temperature-dependent, reversible Li+-ion uptake/release equilibrium at metal oxide nanocontainer pores

被引：82

作者：

Müller, A

Rehder, D

Haupt, ETK

Merca, A

Bögge, H

Schmidtmann, M

Heinze-Brückner, G

机构：

[1] Univ Bielefeld, Fak Chem, Lehrstuhl Anorgan Chem 1, D-33501 Bielefeld, Germany

[2] Univ Hamburg, Inst Anorgan & Angew Chem, D-20146 Hamburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 34期

关键词：

artificial cells; ion channels; lithium; nanostructures; porous materials;

D O I：

10.1002/anie.200453762

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium ion trafficking: Surprisingly stable and soluble spherical molybdenum oxide based porous nanocontainers/artificial cells (see graphic) interact specifically with their environment, for example, with cations abundant in solution, to incorporate them at well-defined internal cell positions. In the present case, the traffic of Li+ ions between the "outside and inside" is in equilibrium (homeostasis) as measured by NMR spectroscopy. (Li purple, Mo blue, O red).

引用

页码：4466 / 4470

页数：5

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[Anonymous], [No title captured]

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