Brush Polymer Ion Gels

被引：26

作者：

Bates, Christopher M. ^{[1
]}

Chang, Alice B. ^{[1
]}

Schulze, Morgan W. ^{[2
]}

Momcilovic, Nebojsa ^{[1
]}

Jones, Simon C. ^{[3
]}

Grubbs, Robert H. ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

[2] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA

[3] CALTECH, Jet Prop Lab, Electrochem Technol Grp, Pasadena, CA 91109 USA

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 2016年 / 54卷 / 02期

关键词：

block polymer; brush polymer; ion gel; ionic liquid; scattering; TRIBLOCK COPOLYMER; MOLECULAR-WEIGHT; LOW-VOLTAGE; CONDUCTIVITY; ELECTROLYTES; BEHAVIOR; LIQUID;

D O I：

10.1002/polb.23927

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

The structure, rheological response, and ionic conductivity of ABA brush block copolymer (BBCP) ion gels containing 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMI][TFSI]) at polymer concentrations spanning 5-50 wt % (Phi(gel)) were studied by small angle X-ray scattering, dynamic mechanical analysis, and AC impedance spectroscopy. Application of a hard sphere form factor and Percus-Yevick structure factor reveals trends in gel micellar structure as a function of BBCP molecular weight, A block volume fraction (Phi(A)), and Phi(gel). Viscoelastic properties are strongly dependent on end-block molar mass, with storage moduli <= 10(3) Pa at 25 degrees C. Impedance measurements reveal near liquid-like dynamics in the matrix phase as evidenced by conductivities near 1 mS/cm at 25 degrees C that decrease with increasing Phi(gel) and Phi(A). (C) 2015 Wiley Periodicals, Inc.

引用

页码：292 / 300

页数：9

共 35 条

[1]

ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties [J].

Bates, Christopher M. ;

Chang, Alice B. ;

Momcilovic, Nebojsa ;

Jones, Simon C. ;

Grubbs, Robert H. .

MACROMOLECULES, 2015, 48 (14) :4967-4973

[2]

Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic [J].

Cho, Jeong Ho ;

Lee, Jiyoul ;

Xia, Yu ;

Kim, Bongsoo ;

He, Yiyong ;

Renn, Michael J. ;

Lodge, Timothy P. ;

Frisbie, C. Daniel .

NATURE MATERIALS, 2008, 7 (11) :900-906

[3]

Linear Rheology of Polyolefin-Based Bottlebrush Polymers [J].

Dalsin, Samuel J. ;

Hillmyer, Marc A. ;

Bates, Frank S. .

MACROMOLECULES, 2015, 48 (13) :4680-4691

[4]

Molecular Weight Dependence of Zero-Shear Viscosity in Atactic Polypropylene Bottlebrush Polymers [J].

Dalsin, Samuel J. ;

Hillmyer, Marc A. ;

Bates, Frank S. .

ACS MACRO LETTERS, 2014, 3 (05) :423-427

[5]

Aqueous Self-Assembly of Giant Bottlebrush Block Copolymer Surfactants as Shape-Tunable Building Blocks [J].

Fenyves, Ryan ;

Schmutz, Marc ;

Horner, Ian J. ;

Bright, Frank V. ;

Rzayev, Javid .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (21) :7762-7770

[6]

High Toughness, High Conductivity Ion Gels by Sequential Triblock Copolymer Self-Assembly and Chemical Cross-Linking [J].

Gu, Yuanyan ;

Zhang, Sipei ;

Martinetti, Luca ;

Lee, Keun Hyung ;

McIntosh, Lucas D. ;

Frisbie, C. Daniel ;

Lodge, Timothy P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (26) :9652-9655

[7]

Structure and Nanostructure in Ionic Liquids [J].

Hayes, Robert ;

Warr, Gregory G. ;

Atkin, Rob .

CHEMICAL REVIEWS, 2015, 115 (13) :6357-6426

[8]

Ion gels by self-assembly of a triblock copolymer in an ionic liquid [J].

He, Yiyong ;

Boswell, Paul G. ;

Buhlmann, Philippe ;

Lodge, Timothy P. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18) :4645-4652

[9]

Heimenz PC, 2007, POLYM CHEM

[10]

Linear Rheological Response of a Series of Densely Branched Brush Polymers [J].

Hu, Miao ;

Xia, Yan ;

McKenna, Gregory B. ;

Kornfield, Julia A. ;

Grubbs, Robert H. .

MACROMOLECULES, 2011, 44 (17) :6935-6943

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