Remarkably robust group 4 metal half-sandwich complexes containing two higher alkyl ligands: X-ray structure and reactivity of the di-n-butyl complex [Hf(eta(5):eta(1):eta(1)-C5Me4SiMe2NCH2CH2OMe)Bu-n(2)]

被引：36

作者：

Amor, F ^{[1
]}

Spaniol, TP ^{[1
]}

Okuda, J ^{[1
]}

机构：

[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55099 MAINZ,GERMANY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 22期

关键词：

D O I：

10.1021/om970446x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of LiR with M(eta(5):eta(1):eta(1)-C5Me4SiMe2NCH2CH2OMe)Cl-2 (1, M = Zr (a), Hf (b)) gives the isolable, thermally stable complexes M(eta(5):eta(1):eta(1)-C5Me4SiMe2NCH2CH2OMe)R-2 (R = Et(2), Pr-n (3), Bu-n (4)), which contain two alkyl ligands with beta-hydrogen atoms.

引用

页码：4765 / 4767

页数：3

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