Acidity dependence of the trifluoromethanesulfonic acid catalyzed isobutane-isobutylene alkylation modified with trifluoroacetic acid or water

被引：53

作者：

Olah, GA ^{[1
]}

Batamack, P ^{[1
]}

Deffieux, D ^{[1
]}

Torok, B ^{[1
]}

Wang, Q ^{[1
]}

Molnar, A ^{[1
]}

Prakash, GKS ^{[1
]}

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

来源：

APPLIED CATALYSIS A-GENERAL | 1996年 / 146卷 / 01期

关键词：

alkylation; isobutane; isobutylene; trifluoromethanesulfonic acid;

D O I：

10.1016/0926-860X(96)00045-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Trifluoromethanesulfonic acid (TFSA) catalyzed isobutane-isobutylene alkylation modified with trifluoroacetic acid (TFA) or water, was studied over a wide range of acidity (Ho: - 10.1 to - 14.1). The effect of the acidity of these nonoxidizing strong mixed acid systems on the alkylation, is reported. For both systems, the best alkylation conditions were those at an acid strength of about Ho = - 10.7, giving a calculated research octane number (RON) of 89.1 (TFSA/TFA) and 91.3 (TFSA/H2O).

引用

页码：107 / 117

页数：11

共 17 条

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