Chemometrics tools used in analytical chemistry: An overview

被引：287

作者：

Kumar, Naveen ^{[1
]}

Bansal, Ankit ^{[1
]}

Sarma, G. S. ^{[1
]}

Rawal, Ravindra K. ^{[1
]}

机构：

[1] Indosoviet Coll Pharm ISFCP, Dept Pharmaceut Anal, Moga 142001, India

来源：

TALANTA | 2014年 / 123卷

关键词：

Singular value decomposition; Evolving factor analysis; Chemometrics Rank annihilation; Multivariate calibration; Principal component; PERFORMANCE LIQUID-CHROMATOGRAPHY; PARTIAL-LEAST-SQUARES; SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION; MULTIVARIATE CURVE RESOLUTION; DIODE-ARRAY DETECTION; ANNIHILATION FACTOR-ANALYSIS; PRINCIPAL COMPONENT ANALYSIS; EVOLVING LATENT PROJECTIONS; 2-WAY MULTICOMPONENT DATA; RANK ANNIHILATION;

D O I：

10.1016/j.talanta.2014.02.003

中图分类号：

O65 [分析化学];

学科分类号：

070302 [分析化学];

摘要：

This article presents various important tools of chemometrics utilized as data evaluation tools generated by various hyphenated analytical techniques including their application since its advent to today. The work has been divided into various sections, which include various multivariate regression methods and multivariate resolution methods. Finally the last section deals with the applicability of chemometric tools in analytical chemistry. The main objective of this article is to review the chemometric methods used in analytical chemistry (qualitative/quantitative), to determine the elution sequence, classify various data sets, assess peak purity and estimate the number of chemical components. These reviewed methods further can be used for treating n-way data obtained by hyphenation of LC with multi-channel detectors. We prefer to provide a detailed view of various important methods developed with their algorithm in favor of employing and understanding them by researchers not very familiar with chemometrics. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：186 / 199

页数：14

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