Coordinated carbenes from electron-rich olefins on RuHCl(PPri3)2

Dehydrohalogenation of RuH2Cl2L2 (L = PPr3i) gives (RuHClL2)(2), shown to be a halide-bridged dimer by X-ray crystallography; the fluoride analog is also a dimer. (RuHClL2)(2) reacts with N-2, pyridine and C2H4 (L') to give RuHCIL'L-2, but with vinyl ether and vinyl amides, H2C=CH(E) [E = OR, NRC(O)R'] such olefin binding is followed by isomerization to the heteroatom-substituted carbene complex L2HClRu=C(CH3)(E), The reaction mechanism for such rearrangement is established by DFT(B3PW91) computations, for C2H4 as olefin (where it is found to be endothermic), and the structures of intermediates are calculated for H2C=C(H)(OCH3) and for cyclic and acyclic amide-substituted olefins. It is found, both experimentally and computationally, that the amide oxygen is bonded to Ru with a calculated bond energy of approximately 9 kcal mol(-1) for an acyclic model. Less electron-rich vinyl amides or amines form eta(2)-olefin complexes, but do not isomerize to carbene complexes. Calculated Delta E values for selected "competition" reactions reveal that donation by both Ru and the heteroatom-substituted X are necessary to make the carbene complex L2HClRu=C(X)(CH3) more stable than the olefin complex L2HClRu(eta(2)-H2C=CHX). This originates in part from a diminished endothermicity of the olefin -->, carbene transformation when the sp(2) carbon bears a pi-donor substituent. The importance of a hydride on Ru in furnishing a mechanism for this isomerization is discussed. The compositional characteristics of Schrock and Fischer carbenes are detailed, it is suggested that reactivity will not be uniquely determined by these characteristics, and these new carbenes RuHCl[C(X)CH3]L-2 are contrasted to Schrock and Fischer carbenes.