New palladium carbene catalysts for the Heck reaction of aryl chlorides in ionic liquids

被引:287
作者
Selvakumar, K [1 ]
Zapf, A [1 ]
Beller, M [1 ]
机构
[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany
关键词
D O I
10.1021/ol020103h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The Heck reaction of aryl chlorides was investigated in the presence of defined monocarbenepalladium(0) complexes. Activated and nonactivated aryl chlorides provide the corresponding cinnamic esters and stilbenes in (Bu4NBr)-Bu-n as a ionic liquid in good to excellent yields.
引用
收藏
页码:3031 / 3033
页数:3
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