Synthesis and reactivity of Ru-, Os-, Rh-, and Ir-halide-sulfoxide complexes

被引：204

作者：

Alessio, E ^{[1
]}

机构：

[1] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 09期

关键词：

D O I：

10.1021/cr0307291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Platinum-group metal halide-sulfoxide complexes have a rich chemistry and are widely used as precursors in inorganic synthesis. This report collects and reviews critically the available data concerning the preparation and the spectroscopic and structural characterization of ruthenium-, osmium-, rhodium-, and iridium-halide-dmso compounds. It also gives a comprehensive and detailed report on the use of such compounds as versatile precursors in inorganic synthesis.

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页码：4203 / 4242

页数：40

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