Study of copper foam-supported Sn thin film as a high-capacity anode for lithium-ion batteries

被引:62
作者
Li, Qingyu [1 ]
Hu, Sijiang [1 ]
Wang, Hongqiang [1 ]
Wang, Fangping [1 ]
Zhong, Xinxian [1 ]
Wang, Xinyu [1 ,2 ]
机构
[1] Guangxi Normal Univ, Sch Chem & Chem Engn, Guilin 541004, Peoples R China
[2] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Sn thin film; Negative electrode; Electroless deposition; Copper foam; Lithium-ion batteries; SECONDARY BATTERIES; ELECTROCHEMICAL PROPERTIES; NEGATIVE ELECTRODES; TIN SYSTEM; BEHAVIOR;
D O I
10.1016/j.electacta.2009.05.051
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Three-dimensional porous Sri thin film electrodes were prepared by electroless deposition on copper foam, then its morphology and electrochemical property were studied by means of scanning electron microscope (SEM), X-ray diffraction (XRD), electrochemical cycling test and cyclic voltammetry (CV). The porous framework and micro-holes have shown a great structure advantage in restricting severe volume changes when the Sri thin film was employed as anode for lithium-ion battery. The film electrode of sample C with an initial capacity of 676 mAh g(-1) showed good cycle performance displayed by retaining a capacity of 313 mAh g(-1) after 100 cycles. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5884 / 5888
页数:5
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