Evaluation of alloys synthesized by mechanical alloying as potential anode materials for lithium-ion batteries

被引:2
作者
Wachtler, M [1 ]
Schiffini, L [1 ]
Amadei, I [1 ]
Serra Moreno, J [1 ]
Scrosati, B [1 ]
Cocco, G [1 ]
机构
[1] Univ Roma La Sapienza, Dept Chem, IT-00185 Rome, Italy
来源
ISMANAM 2003: METASTABLE, MECHANICALLY ALLOYED AND NANOCRYSTALLINE MATERIALS | 2004年 / 20-21卷
关键词
lithium battery; lithium storage alloy; mechanical alloying; SHS;
D O I
10.4028/www.scientific.net/JMNM.20-21.263
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Several alloys (Mg2Si, Li4Mg2Si, Sn0.66Sb0.34, and Li4Sn0.72Sb0.28) have been synthesized by mechanical alloying and characterized for their performance as anode materials for Li-ion batteries. Sn0.66Sb0.34 shows a better cycling performance than Mg2Si, whose higher initial capacities fade after a few cycles only. The pre-lithiated materials Li4Mg2Si and Li4Sn0.72Sb0.28 give good cycling stabilities, however, at much smaller capacities than exhibited by their unlithiated counterparts.
引用
收藏
页码:263 / 268
页数:6
相关论文
共 12 条
  • [1] Delogu F, 2000, INT J NON-EQUILIB PR, V11, P235
  • [2] MONAGHEDDU M, 2003, J PHYS D, V36, P1
  • [3] Reaction mechanism of metal silicide Mg2Si for Li insertion
    Moriga, T
    Watanabe, K
    Tsuji, D
    Massaki, S
    Nakabayashi, I
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2000, 153 (02) : 386 - 390
  • [4] Munir Z. A., 1989, Material Science Reports, V3, P277, DOI 10.1016/0920-2307(89)90001-7
  • [5] PELED E, 1999, HDB BATTERY MAT, P419
  • [6] Magnesium silicide as a negative electrode material for lithium-ion batteries
    Roberts, GA
    Cairns, EJ
    Reimer, JA
    [J]. JOURNAL OF POWER SOURCES, 2002, 110 (02) : 424 - 429
  • [7] Mechanical alloying and milling
    Suryanarayana, C
    [J]. PROGRESS IN MATERIALS SCIENCE, 2001, 46 (1-2) : 1 - 184
  • [8] Vaughey JT, 2000, ELECTROCHEM SOLID ST, V3, P13, DOI 10.1149/1.1390944
  • [9] NiAs- versus zinc-blende-type intermetallic insertion electrodes for lithium batteries:: lithium extraction from Li2CuSn
    Vaughey, JT
    Kepler, KD
    Benedek, R
    Thackeray, MM
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 1999, 1 (11) : 517 - 521
  • [10] Anodic materials for rechargeable Li-batteries
    Wachtler, M
    Winter, M
    Besenhard, JO
    [J]. JOURNAL OF POWER SOURCES, 2002, 105 (02) : 151 - 160