Further studies on the polymorphic dithiadiazolyl radical, ClCNSSN

被引:23
作者
Clarke, CS [1 ]
Pascu, SI [1 ]
Rawson, JM [1 ]
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
来源
CRYSTENGCOMM | 2004年 / 6卷
关键词
D O I
10.1039/b403430a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A fourth polymorph of the 4-chloro-1,2,3,5-dithiadiazolyl radical, ClCNSSN is reported. It crystallises as twisted cofacial dimers in the triclinic space group P-1 with four molecules in the asymmetric unit. Whilst the structure exhibits three-centre SSdelta+...Ndelta- motifs similar to those previously observed in the alpha, beta and gamma phases, only 75% of the anticipated number of contacts are observed.
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页码:79 / 82
页数:4
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